METHASOL
International cooperation for selective conversion of CO2 into METHAnol under SOLar light (METHASOL)
Methanol is an appealing energy vector, with attractive volumetric and gravimetric energy values, storable in liquid phase at ambient conditions of pressure and temperature, which can be used as fuel directly or converted into chemicals or gasoline. However, its production lacks a sustainable route. Thus, the METHASOL project aims to produce methanol through a sustainable and cost-effective process based on the selective visible light driven gas phase CO2 reduction, with a solar to methanol energy conversion efficiency of 5%.
During 42 months, METHASOL will gather 14 partners from EU/Associated MS, China and the USA, including some of the world’s most recognized researchers on artificial photosynthesis, to achieve a ground-breaking combination of a CO2 reduction reaction (CO2RR) system based on Metal-Organic Framework (MOF) and a graphitic Carbon Nitride (g-CN) for photocatalytic oxygen evolution reaction (OER), through a Z-scheme heterojunction.
Following the definition of the system specifications, a first set of materials for OER and CO2RR will be synthesized and their photocatalytic activity and stability will be screened. The most promising materials will be further analyzed thanks to experimental characterization and modelling, leading to guidelines used for designing an enhanced CO2RR and OER materials. The best systems will be integrated through a Z-scheme heterojunction, either with or without a mediator, and tested in tailored reactors operating in the gas phase under different conditions. A complete sustainability analysis will be conducted to ensure the clean production of methanol. The cooperation between European and Chinese research entities will be consolidated to last beyond the project lifetime through the creation of a common exploitation plan. Through its ambitious activities on photo-catalyst developed for solar to methanol conversion, METHASOL will propose a new path for decarbonizing Europe.
Timeline: 01/07/2021 - 31/12/2024
Contact: Yvonne van der Meer
